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013 bar, S/C=1 0,8 0,7 0,6 0,5 0,4 0,3 0,2 0,1 0 200 ' Hydrogen rich synthesis gas. 5bar Tinlet=800K z=0 , ! Toutlet=1050K T [K] pinlet=29bar -3 F 7! " & 6= , , ! gov/WWW/CEAWeb/ 1400 1600 < ) $ 35 * 6 ' $ 7! < 3 3 & 3 ' ! Q ) # ,! ' Effects over time at 200mA/cm² and 10ppm CO # 1 + *+ 36 $()7 + / / ' 88 3- ! 1 kg/kW (including H2S-trap) 37 < B Water (For Cooling) Superheater Fuel including sulphur Exhaust <# C 80°C PEM-FC Air CP Water Power densities are set assuming automotive targets are met ~ 1kg/kW.
8 . 7! - 3 Fuel Water Air CnHmOp + $ 5 Reformer Products (Reformate or Syngas) H2, CO2, CO, CH4, N2 General Reforming Reaction (Developed By Argonne National Laboratory): CnHmOp + xO2 + (2n-2x-p)H2O = nCO2 + (2n-2x-p+m/2)H2 Enthalpy of Reaction: –∆Hr = n∆HCO2 – (2n-2x-p)∆HH2O – ∆Hfuel Definition of Reforming: The process of converting liquid or gaseous hydrocarbon fuels into a gas consisting of mainly hydrogen and carbon monoxide. 32 &' , ! 3 FUEL REFORMER (Production of H2 and CO2 from a CH-fuel) Fuel PEMFC H2 + CO2 Anode H2O Reactor Electrolyte Water/air separator Burner Cathode Air Air H2 + CO2 Cooler/Humidifier Air Exhaust Gasses Turbine Compressor Approx.